Alaphilippe had led Yates by four seconds when the race was finished and looked to have retained the yellow jersey, but television footage showed him taking a bottle from a Deceuninck-Quick Step team support member with 17.8km to go - under the rules of cycling's world governing body UCI, riders are not allowed to take on food or drink in the final 20km of a race.
World number one Djokovic struck 51 winners to notch up the win against Edmund, extending his unbeaten run this year to 25 matches.
There were also second round wins for fourth seed Stefanos Tsitsipas of Greece, fifth seed Alexander Zverev of Germany and seventh seed David Goffin of Belgium.
Emre Can (Front, L) of Germany vies with Alcantara Thiago of Spain during a UEFA Nations League match between Germany and Spain in Stuttgart, Germany, Sept. 3, 2020. (Xinhua)
After the restart, Germany got a perfect start as Werner broke the deadlock on 51 minutes after capitalizing on Robin Gosens' square pass into the penalty area.
The 23-year-old Dutchman has signed a five-year contract at Old Trafford, with an option to extend by a further year. The transfer fee is 39 million euros (46 million U.S. dollars), which may increase to 44 million euros if certain clauses are met.
Duplantis tried to challenge Sergei Bubka's 26-year-old outdoor record of 6.14 meters, but failed to continue after one unsuccessful attempt at 6.15 meters as darkness set in.
"It's top players, so if you wait for the mistake it's never going to happen," Garcia said. "If you let Pliskova breeze and take your serve, you're never going to make a return, and then it's 6-4, 6-4 and you're done in one hour."
The 2020/2021 season will provide thrilling games for fans as the leading clubs are close together. "We had only four points between the top three before the pandemic outbreak."
Meanwhile, Spain lacked in penetration and failed to pose danger in front of Germany's goal.
Marouane Fellaini (R) of Shandong Luneng vies with Wu Xi of Jiangsu Suning during the 9th round match between Shandong Luneng and Jiangsu Suning at the postponed 2020 season Chinese Football Association Super League (CSL) Dalian Division in Dalian, northeast China's Liaoning Province, Sept. 3, 2020. (Xinhua/Pan Yulong)